In physics, natural abundance (NA) refers to the abundance of isotopes of a chemical element as naturally found on a planet. The relative atomic mass (a weighted average, weighted by mole-fraction abundance figures) of these isotopes is the atomic weight listed for the element in the periodic table. The abundance of an isotope varies from planet to planet, and even from place to place on the Earth, but remains relatively constant in time (on a short-term scale).
As an example, uranium has three naturally occurring isotopes: 238U, 235U and 234U. Their respective natural mole-fraction abundances are 99.2739–99.2752%, 0.7198–0.7202%, and 0.0050–0.0059%.[1] For example, if 100,000 uranium atoms were analyzed, one would expect to find approximately 99,274 238U atoms, approximately 720 235U atoms, and very few (most likely 5 or 6) 234U atoms. This is because 238U is much more stable than 235U or 234U, as the half-life of each isotope reveals: 4.468 × 109 years for 238U compared with 7.038 × 108 years for 235U and 245,500 years for 234U.
Exactly because the different uranium isotopes have different half-lives, when the Earth was younger, the isotopic composition of uranium was different. As an example, 1.7×109 years ago the NA of 235U was 3.1% compared with today's 0.7%, and for that reason a natural nuclear fission reactor was able to form, something that cannot happen today.
However, the natural abundance of a given isotope is also affected by the probability of its creation in nucleosynthesis (as in the case of samarium; radioactive 147Sm and 148Sm are much more abundant than stable 144Sm) and by production of a given isotope as a daughter of natural radioactive isotopes (as in the case of radiogenic isotopes of lead).
Deviations from natural abundance
It is now known from study of the sun and primitive meteorites that the solar system was initially almost homogeneous in isotopic composition. Deviations from the (evolving) galactic average, locally sampled around the time that the sun's nuclear burning began, can generally be accounted for by mass fractionation (see the article on mass-independent fractionation) plus a limited number of nuclear decay and transmutation processes.[2] There is also evidence for injection of short-lived (now extinct) isotopes from a nearby supernova explosion that may have triggered solar nebula collapse.[3] Hence deviations from natural abundance on earth are often measured in parts per thousand (per mille or ‰) because they are less than one percent (%).
The single exception to this lies with the presolar grains found in primitive meteorites. These bypassed the homogenization , and often carry the nuclear signature of specific nucleosynthesis processes in which their elements were made.[4] In these materials, deviations from "natural abundance" are sometimes measured in factors of 100.
Natural abundance of some elements
The next table gives the terrestrial isotope distributions for some elements. Some elements like phosphorus and fluorine only exist as a single isotope, with a natural abundance of 100%.
Natural abundance of some elements [5] Isotope % nat. abundance atomic mass
1H 99.985 1.007825
2H 0.015 2.0140
12C 98.89 12 (formerly by definition)
13C 1.11 13.00335
14N 99.64 14.00307
15N 0.36 15.00011
16O 99.76 15.99491
17O 0.04 16.99913
18O 0.2 17.99916
28Si 92.23 27.97693
29Si 4.67 28.97649
30Si 3.10 29.97376
32S 95.0 31.97207
33S 0.76 32.97146
34S 4.22 33.96786
35Cl 75.77 34.96885
37Cl 24.23 36.96590
79Br 50.69 78.9183
81Br 49.31 80.9163
See also
Abundance of the chemical elements
Decay product
Isotope
Presolar grains
Radionuclide
Footnotes and References
Uranium Isotopes, retrieved 14 March 2012
Clayton, Robert N. (1978). "Isotopic anomalies in the early solar system". Annual Review of Nuclear and Particle Science. 28: 501–522. Bibcode:1978ARNPS..28..501C. doi:10.1146/annurev.ns.28.120178.002441.
Zinner, Ernst (2003). "An isotopic view of the early solar system". Science. 300 (5617): 265–267. doi:10.1126/science.1080300. PMID 12690180.
Zinner, Ernst (1998). "Stellar nucleosynthesis and the isotopic composition of presolar grains from primitive meteorites". Annual Review of Earth and Planetary Sciences. 26: 147–188. Bibcode:1998AREPS..26..147Z. doi:10.1146/annurev.earth.26.1.147.
Lide, D. R., ed. (2002). CRC Handbook of Chemistry and Physics (83rd ed.). Boca Raton, FL: CRC Press. ISBN 0-8493-0483-0.
External links
Berkeley Isotopes Project Interactive Table
Scientific Instrument Services List
Tools to compute low and high precision isotopic distribution
Hellenica World - Scientific Library
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