Mott insulators are a class of materials that should conduct electricity under conventional band theories, but are in fact insulators when measured (particularly at low temperatures). This effect is due to electron–electron interactions, which are not considered in conventional band theory.
The bandgap in a Mott insulator exists between bands of like character, such as 3d character, whereas the bandgap in charge transfer insulators exists between anion and cation states,[1] such as between O 2p and Ni 3d bands in NiO.[2]
History
Although the band theory of solids had been very successful in describing various electrical properties of materials, in 1937 Jan Hendrik de Boer and Evert Johannes Willem Verwey pointed out that a variety of transition metal oxides predicted to be conductors by band theory (because they have an odd number of electrons per unit cell) are insulators.[3] Nevill Mott and Rudolf Peierls then (also in 1937) predicted that this anomaly can be explained by including interactions between electrons.[4]
In 1949, in particular, Mott proposed a model for NiO as an insulator, where conduction is based on the formula[5]
(Ni2+O2−)2 → Ni3+O2− + Ni1+O2−.
In this situation, the formation of an energy gap preventing conduction can be understood as the competition between the Coulomb potential U between 3d electrons and the transfer integral t of 3d electrons between neighboring atoms (the transfer integral is a part of the tight binding approximation). The total energy gap is then
Egap = U − 2zt,
where z is the number of nearest-neighbor atoms.
In general, Mott insulators occur when the repulsive Coulomb potential U is large enough to create an energy gap. One of the simplest theories of Mott insulators is the 1963 Hubbard model. The crossover from a metal to a Mott insulator as U is increased can be predicted within the so-called dynamical mean field theory.
Mottness
Mottism denotes the additional ingredient, aside from antiferromagnetic ordering, which is necessary to fully describe a Mott Insulator. In other words, we might write: antiferromagnetic order + mottism = Mott insulator.
Thus, mottism accounts for all of the properties of Mott insulators that cannot be attributed simply to antiferromagnetism.
There are a number of properties of Mott insulators, derived from both experimental and theoretical observations, which cannot be attributed to antiferromagnetic ordering and thus constitute mottism. These properties include:
Spectral weight transfer on the Mott scale[6][7]
Vanishing of the single particle Green function along a connected surface in momentum space in the first Brillouin zone[8]
Two sign changes of the Hall coefficient as electron doping goes from n=0 to n=2 (band insulators have only one sign change at n=1)
The presence of a charge 2e (with e<0 the charge of an electron) boson at low energies[9][10]
A pseudogap away from half-filling ( n=1)[11]
Applications
Mott insulators are of growing interest in advanced physics research, and are not yet fully understood. They have applications in thin-film magnetic heterostructures and the strong correlated phenomena in high-temperature superconductivity, for example.[12][13][14][15]
This kind of insulator can become a conductor by changing some parameters, which may be composition, pressure, strain, voltage, or magnetic field. The effect is known as a Mott transition and can be used to build smaller field-effect transistors, switches and memory devices than possible with conventional materials.[16][17][18]
See also
Dynamical mean field theory
Electronic band structure
Hubbard model
Metal–insulator transition
Mott criterion
Tight-binding approximation
Variable-range hopping (Mott)
Notes
lecture slides
P. Kuiper; G. Gruizinga; J. Ghijsen; G.A. Sawatzky; H. Verweij (1987). "Character of Holes in LixNi1−xO2". Physical Review Letters. 62 (2): 221–224. Bibcode:1989PhRvL..62..221K. doi:10.1103/PhysRevLett.62.221. PMID 10039954.
de Boer, J. H.; Verwey, E. J. W. (1937). "Semi-conductors with partially and with completely filled 3d-lattice bands". Proceedings of the Physical Society. 49 (4S): 59. Bibcode:1937PPS....49...59B. doi:10.1088/0959-5309/49/4S/307.
Mott, N. F.; Peierls, R. (1937). "Discussion of the paper by de Boer and Verwey". Proceedings of the Physical Society. 49 (4S): 72. Bibcode:1937PPS....49...72M. doi:10.1088/0959-5309/49/4S/308.
Mott, N. F. (1949). "The basis of the electron theory of metals, with special reference to the transition metals". Proceedings of the Physical Society. Series A. 62 (7): 416–422. Bibcode:1949PPSA...62..416M. doi:10.1088/0370-1298/62/7/303.
Phillips, Philip (2006). "Mottness". Annals of Physics. Elsevier BV. 321 (7): 1634–1650.arXiv:cond-mat/0702348. Bibcode:2006AnPhy.321.1634P. doi:10.1016/j.aop.2006.04.003. ISSN 0003-4916.
Meinders, M. B. J.; Eskes, H.; Sawatzky, G. A. (1993-08-01). "Spectral-weight transfer: Breakdown of low-energy-scale sum rules in correlated systems". Physical Review B. American Physical Society (APS). 48 (6): 3916–3926. Bibcode:1993PhRvB..48.3916M. doi:10.1103/physrevb.48.3916. ISSN 0163-1829. PMID 10008840.
Stanescu, Tudor D.; Phillips, Philip; Choy, Ting-Pong (2007-03-06). "Theory of the Luttinger surface in doped Mott insulators". Physical Review B. American Physical Society (APS). 75 (10): 104503.arXiv:cond-mat/0602280. Bibcode:2007PhRvB..75j4503S. doi:10.1103/physrevb.75.104503. ISSN 1098-0121.
Leigh, Robert G.; Phillips, Philip; Choy, Ting-Pong (2007-07-25). "Hidden Charge 2e Boson in Doped Mott Insulators". Physical Review Letters. 99 (4): 046404.arXiv:cond-mat/0612130v3. Bibcode:2007PhRvL..99d6404L. doi:10.1103/physrevlett.99.046404. ISSN 0031-9007. PMID 17678382.
Choy, Ting-Pong; Leigh, Robert G.; Phillips, Philip; Powell, Philip D. (2008-01-17). "Exact integration of the high energy scale in doped Mott insulators". Physical Review B. American Physical Society (APS). 77 (1): 014512. arXiv:0707.1554. Bibcode:2008PhRvB..77a4512C. doi:10.1103/physrevb.77.014512. ISSN 1098-0121.
Stanescu, Tudor D.; Phillips, Philip (2003-07-02). "Pseudogap in Doped Mott Insulators is the Near-Neighbor Analogue of the Mott Gap". Physical Review Letters. 91 (1): 017002. arXiv:cond-mat/0209118. Bibcode:2003PhRvL..91a7002S. doi:10.1103/physrevlett.91.017002. ISSN 0031-9007. PMID 12906566.
Kohsaka, Y.; Taylor, C.; Wahl, P.; et al. (August 28, 2008). "How Cooper pairs vanish approaching the Mott insulator in Bi2Sr2CaCu2O8+δ". Nature. 454 (7208): 1072–1078. arXiv:0808.3816. Bibcode:2008Natur.454.1072K. doi:10.1038/nature07243. PMID 18756248. S2CID 205214473.
Markiewicz, R. S.; Hasan, M. Z.; Bansil, A. (2008-03-25). "Acoustic plasmons and doping evolution of Mott physics in resonant inelastic x-ray scattering from cuprate superconductors". Physical Review B. 77 (9): 094518. Bibcode:2008PhRvB..77i4518M. doi:10.1103/PhysRevB.77.094518.
Hasan, M. Z.; Isaacs, E. D.; Shen, Z.-X.; Miller, L. L.; Tsutsui, K.; Tohyama, T.; Maekawa, S. (2000-06-09). "Electronic Structure of Mott Insulators Studied by Inelastic X-ray Scattering". Science. 288 (5472): 1811–1814. arXiv:cond-mat/0102489. Bibcode:2000Sci...288.1811H. doi:10.1126/science.288.5472.1811. ISSN 0036-8075. PMID 10846160. S2CID 2581764.
Hasan, M. Z.; Montano, P. A.; Isaacs, E. D.; Shen, Z.-X.; Eisaki, H.; Sinha, S. K.; Islam, Z.; Motoyama, N.; Uchida, S. (2002-04-16). "Momentum-Resolved Charge Excitations in a Prototype One-Dimensional Mott Insulator". Physical Review Letters. 88 (17): 177403. arXiv:cond-mat/0102485. Bibcode:2002PhRvL..88q7403H. doi:10.1103/PhysRevLett.88.177403. PMID 12005784. S2CID 30809135.
Newns, Dennis (2000). "Junction mott transition field effect transistor (JMTFET) and switch for logic and memory applications". http://www.google.com/patents/US6121642
Zhou, You; Ramanathan, Shriram (2013-01-01). "Correlated Electron Materials and Field Effect Transistors for Logic: A Review". Critical Reviews in Solid State and Materials Sciences. 38 (4): 286–317. arXiv:1212.2684. Bibcode:2013CRSSM..38..286Z. doi:10.1080/10408436.2012.719131. ISSN 1040-8436. S2CID 93921400.
Son, Junwoo; et al. (2011-10-18). "A heterojunction modulation-doped Mott transistor". Applied Physics Letters. 110 (8): 084503–084503–4. arXiv:1109.5299. Bibcode:2011JAP...110h4503S. doi:10.1063/1.3651612. S2CID 27583830.
References
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Jördens, Robert; Strohmaier, Niels; Günter, Kenneth; Moritz, Henning; Esslinger, Tilman (2008). "A Mott insulator of fermionic atoms in an optical lattice". Nature. 455 (7210): 204–207.arXiv:0804.4009. Bibcode:2008Natur.455..204J. doi:10.1038/nature07244. PMID 18784720. S2CID 4426395.
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