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A Langmuir–Taylor detector, also called surface ionization detector or hot wire detector, is a kind of ionization detector used in mass spectrometry, developed by John Taylor[1] based on the work of Irving Langmuir and K. H. Kingdon.[2]

Construction

This detector usually consists of a heated thin filament or ribbon of a metal with a high work function (typically tungsten or rhenium). Neutral atoms or molecules that strike the filament can boil off as positive ions in a process known as surface ionization, and these may be either measured as a current or detected, individually, using an electron multiplier and particle counting electronics.
Applications

This detector is mostly used with alkali atoms, having a low ionization potential, with applications in mass spectrometry and atomic clocks.
References

Taylor, John (1930). "The Reflection of Beams of the Alkali Metals from Crystals". Physical Review. 35 (4): 375–380. Bibcode:1930PhRv...35..375T. doi:10.1103/PhysRev.35.375.

Langmuir, Irving (1925). "Thermionic Effects Caused by Vapours of Alkali Metals". Proceedings of the Royal Society A. 107 (741): 61–79. Bibcode:1925RSPSA.107...61L. doi:10.1098/rspa.1925.0005.

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Mass spectrometry

Mass m/z Mass spectrum MS software Acronyms

Ion source

AMS APCI APLI APPI CI DAPPI DART DESI DIOS EESI EI ESI FAB FD GD IA ICP LAESI MALDI MALDESI MIP PTR SESI SIMS SS SSI SELDI TI TS

Mass analyzer

Sector Wien filter Time-of-flight Quadrupole mass filter Quadrupole ion trap Penning trap FT-ICR Orbitrap

Detector

Electron multiplier Microchannel plate detector Daly detector Faraday cup Langmuir–Taylor detector

MS combination

MS/MS QqQ Hybrid MS GC/MS LC/MS IMS/MS CE-MS

Fragmentation

BIRD CID ECD EDD ETD HCD IRMPD NETD SID

Chemistry Encyclopedia

World

Index

Hellenica World - Scientific Library

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